Method of hydrophobizing ejection face of printhead

ABSTRACT

A method of hydrophobizing an ejection face of a printhead is provided which avoids hydrophobizing fluid distribution structures of the printhead. The method involves (a) filling fluid distribution structures of the printhead exposed to the ejection face with a liquid, and (b) depositing a hydrophobizing material onto the ejection face of the printhead, provided that step (a) is performed prior to step (b).

CROSS REFERENCE TO RELATED APPLICATION

This application is a continuation of U.S. application Ser. No. 12/264,903 filed Nov. 4, 2008, which is a continuation of Ser. No. 12/017,771 filed on Jan. 22, 2008, now issued U.S. Pat. No. 7,469,997, which is a continuation application of U.S. patent application Ser. No. 11/097,266 filed on Apr. 4, 2005, now issued U.S. Pat. No. 7,344,226, all of which is herein incorporated by reference.

CO-PENDING APPLICATIONS

The following application has been filed by the Applicant with U.S. Pat. No. 7,344,226:

-   -   U.S. Pat. No. 7,328,976

The disclosure of this co-pending application are incorporated herein by reference.

CROSS REFERENCES TO RELATED APPLICATIONS

The following patents or patent applications filed by the applicant or assignee of the present invention are hereby incorporated by cross-reference.

6,750,901 6,476,863 6,788,336 7,364,256 7,258,417 7,293,853 7,328,968 7,270,395 7,461,916 7,510,264 7,334,864 7,255,419 7,284,819 7,229,148 7,258,416 7,273,263 7,270,393 6,984,017 7,347,526 7,357,477 7,465,015 7,364,255 7,357,476 7,758,148 7,284,820 7,341,328 7,246,875 7,322,669 6,623,101 6,406,129 6,505,916 6,457,809 6,550,895 6,457,812 7,152,962 6,428,133 7,204,941 7,282,164 7,465,342 7,278,727 7,417,141 7,452,989 7,367,665 7,138,391 7,153,956 7,423,145 7,456,277 7,550,585 7,122,076 7,148,345 7,416,280 7,156,508 7,159,972 7,083,271 7,165,834 7,080,894 7,201,469 7,090,336 7,156,489 7,413,283 7,438,385 7,083,257 7,258,422 7,255,423 7,219,980 7,591,533 7,416,274 7,367,649 7,118,192 7,618,121 7,322,672 7,077,505 7,198,354 7,077,504 7,614,724 7,198,355 7,401,894 7,322,676 7,152,959 7,213,906 7,178,901 7,222,938 7,108,353 7,104,629 7,246,886 7,128,400 7,108,355 6,991,322 7,287,836 7,118,197 7,575,298 7,364,269 7,077,493 6,962,402 7,686,429 7,147,308 7,524,034 7,118,198 7,168,790 7,172,270 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FIELD OF THE INVENTION

The present invention relates to the field of inkjet printers and, discloses an inkjet printing system using printheads manufactured with microelectro-mechanical systems (MEMS) techniques.

BACKGROUND OF THE INVENTION

Many different types of printing have been invented, a large number of which are presently in use. The known forms of print have a variety of methods for marking the print media with a relevant marking media. Commonly used forms of printing include offset printing, laser printing and copying devices, dot matrix type impact printers, thermal paper printers, film recorders, thermal wax printers, dye sublimation printers and ink jet printers both of the drop on demand and continuous flow type. Each type of printer has its own advantages and problems when considering cost, speed, quality, reliability, simplicity of construction and operation etc.

In recent years, the field of ink jet printing, wherein each individual pixel of ink is derived from one or more ink nozzles has become increasingly popular primarily due to its inexpensive and versatile nature.

Many different techniques on ink jet printing have been invented. For a survey of the field, reference is made to an article by J Moore, “Non-Impact Printing: Introduction and Historical Perspective”, Output Hard Copy Devices, Editors R Dubeck and S Sherr, pages 207-220 (1988).

Ink Jet printers themselves come in many different types. The utilization of a continuous stream of ink in ink jet printing appears to date back to at least 1929 wherein U.S. Pat. No. 1,941,001 by Hansell discloses a simple form of continuous stream electro-static ink jet printing.

U.S. Pat. No. 3,596,275 by Sweet also discloses a process of a continuous ink jet printing including the step wherein the ink jet stream is modulated by a high frequency electro-static field so as to cause drop separation. This technique is still utilized by several manufacturers including Elmjet and Scitex (see also U.S. Pat. No. 3,373,437 by Sweet et al)

Piezoelectric ink jet printers are also one form of commonly utilized ink jet printing device. Piezoelectric systems are disclosed by Kyser et. al. in U.S. Pat. No. 3,946,398 (1970) which utilizes a diaphragm mode of operation, by Zolten in U.S. Pat. No. 3,683,212 (1970) which discloses a squeeze mode of operation of a piezoelectric crystal, Stemme in U.S. Pat. No. 3,747,120 (1972) discloses a bend mode of piezoelectric operation, Howkins in U.S. Pat. No. 4,459,601 discloses a piezoelectric push mode actuation of the ink jet stream and Fischbeck in U.S. Pat. No. 4,584,590 which discloses a shear mode type of piezoelectric transducer element.

Recently, thermal ink jet printing has become an extremely popular form of ink jet printing. The ink jet printing techniques include those disclosed by Endo et al in GB 2007162 (1979) and Vaught et al in U.S. Pat. No. 4,490,728. Both the aforementioned references disclosed ink jet printing techniques that rely upon the activation of an electrothermal actuator which results in the creation of a bubble in a constricted space, such as a nozzle, which thereby causes the ejection of ink from an aperture connected to the confined space onto a relevant print media. Printing devices utilizing the electro-thermal actuator are manufactured by manufacturers such as Canon and Hewlett Packard.

As can be seen from the foregoing, many different types of printing technologies are available. Ideally, a printing technology should have a number of desirable attributes. These include inexpensive construction and operation, high speed operation, safe and continuous long term operation etc. Each technology may have its own advantages and disadvantages in the areas of cost, speed, quality, reliability, power usage, simplicity of construction operation, durability and consumables.

In the construction of any inkjet printing system, there are a considerable number of important factors which must be traded off against one another especially as large scale printheads are constructed, especially those of a pagewidth type. A number of these factors are outlined in the following paragraphs.

Firstly, inkjet printheads are normally constructed utilizing micro-electromechanical systems (MEMS) techniques. As such, they tend to rely upon standard integrated circuit construction/fabrication techniques of depositing planar layers on a silicon wafer and etching certain portions of the planar layers. Within silicon circuit fabrication technology, certain techniques are better known than others. For example, the techniques associated with the creation of CMOS circuits are likely to be more readily used than those associated with the creation of exotic circuits including ferroelectrics, galium arsenide etc. Hence, it is desirable, in any MEMS constructions, to utilize well proven semi-conductor fabrication techniques which do not require any “exotic” processes or materials. Of course, a certain degree of trade off will be undertaken in that if the advantages of using the exotic material far out weighs its disadvantages then it may become desirable to utilize the material anyway. However, if it is possible to achieve the same, or similar, properties using more common materials, the problems of exotic materials can be avoided.

A desirable characteristic of inkjet printheads would be a hydrophobic nozzle (front) face, preferably in combination with hydrophilic nozzle chambers and ink supply channels. This combination is optimal for ink ejection. Moreover, a hydrophobic front face minimizes the propensity for ink to flood across the front face of the printhead. With a hydrophobic front face, the aqueous inkjet ink is less likely to flood sideways out of the nozzle openings and more likely to form spherical, ejectable microdroplets.

However, whilst hydrophobic front faces and hydrophilic ink chambers are desirable, there is a major problem in fabricating such printheads by MEMS techniques. The final stage of MEMS printhead fabrication is typically ashing of photoresist using an oxygen plasma. However, any organic, hydrophobic material deposited onto the front face will typically be removed by the ashing process to leave a hydrophilic surface. Accordingly, the deposition of hydrophobic material needs to occur after ashing. However, a problem with post-ashing deposition of hydrophobic materials is that the hydrophobic material will be deposited inside nozzle chambers as well as on the front face of the printhead. With no photoresist to protect the nozzle chambers, the nozzle chamber walls become hydrophobized, which is highly undesirable in terms of generating a positive ink pressure biased towards the nozzle chambers. This is a conundrum, which has to date not been addressed in printhead fabrication.

Accordingly, it would be desirable to provide a printhead fabrication process, in which the resultant printhead chip has improved surface characteristics, without comprising the surface characteristics of nozzle chambers. It would further be desirable to provide a printhead fabrication process, in which the resultant printhead chip has a hydrophobic front face in combination with hydrophilic nozzle chambers.

SUMMARY OF THE INVENTION

In a first aspect, there is provided a printhead comprising a plurality of nozzles formed on a substrate, each nozzle comprising a nozzle chamber, a nozzle opening defined in a roof of the nozzle chamber and an actuator for ejecting ink through the nozzle opening, wherein at least part of an ink ejection face of the printhead is hydrophobic relative to the inside surfaces of each nozzle chamber.

In a second aspect, there is provided a method of hydrophobizing an ink ejection face of a printhead, whilst avoiding hydrophobizing nozzle chambers and/or ink supply channels, the method comprising the steps of:

(a) filling nozzle chambers on the printhead with a liquid; and

(b) depositing a hydrophobizing material onto the ink ejection face of the printhead.

BRIEF DESCRIPTION OF THE DRAWINGS

Notwithstanding any other forms that may fall within the scope of the present invention, preferred forms of the invention will now be described, by way of example only, with reference to the accompanying drawings in which:

FIG. 1 is a schematic cross-sectional view through an ink chamber of a unit cell of a printhead according to an embodiment using a bubble forming heater element;

FIG. 2 is a schematic cross-sectional view through the ink chamber FIG. 1, at another stage of operation;

FIG. 3 is a schematic cross-sectional view through the ink chamber FIG. 1, at yet another stage of operation;

FIG. 4 is a schematic cross-sectional view through the ink chamber FIG. 1, at yet a further stage of operation; and

FIG. 5 is a diagrammatic cross-sectional view through a unit cell of a printhead in accordance with an embodiment of the invention showing the collapse of a vapor bubble.

FIG. 6 is a schematic, partially cut away, perspective view of a further embodiment of a unit cell of a printhead.

FIG. 7 is a schematic, partially cut away, exploded perspective view of the unit cell of FIG. 6.

FIG. 8 is a schematic, partially cut away, perspective view of a further embodiment of a unit cell of a printhead.

FIG. 9 is a schematic, partially cut away, exploded perspective view of the unit cell of FIG. 8.

FIG. 10 is a schematic, partially cut away, perspective view of a further embodiment of a unit cell of a printhead.

FIG. 11 is a schematic, partially cut away, exploded perspective view of the unit cell of FIG. 10.

FIG. 12 is a schematic, partially cut away, perspective view of a further embodiment of a unit cell of a printhead.

FIG. 13 is a schematic, partially cut away, perspective view of a further embodiment of a unit cell of a printhead.

FIG. 14 is a schematic, partially cut away, exploded perspective view of the unit cell of FIG. 13.

FIGS. 15 to 25 are schematic perspective views of the unit cell shown in FIGS. 13 and 14, at various successive stages in the production process of the printhead.

FIG. 26 shows partially cut away schematic perspective views of the unit cell of FIG. 25.

FIG. 27 shows the unit cell of FIG. 25 primed with a fluid.

FIG. 28 shows the unit cell of FIG. 27 with a hydrophobic coating on the nozzle plate

DESCRIPTION OF OPTIONAL EMBODIMENTS Bubble Forming Heater Element Actuator

With reference to FIGS. 1 to 4, the unit cell 1 of a printhead according to an embodiment of the invention comprises a nozzle plate 2 with nozzles 3 therein, the nozzles having nozzle rims 4, and apertures 5 extending through the nozzle plate. The nozzle plate 2 is plasma etched from a silicon nitride structure which is deposited, by way of chemical vapor deposition (CVD), over a sacrificial material which is subsequently etched.

The printhead also includes, with respect to each nozzle 3, side walls 6 on which the nozzle plate is supported, a chamber 7 defined by the walls and the nozzle plate 2, a multi-layer substrate 8 and an inlet passage 9 extending through the multi-layer substrate to the far side (not shown) of the substrate. A looped, elongate heater element 10 is suspended within the chamber 7, so that the element is in the form of a suspended beam. The printhead as shown is a microelectromechanical system (MEMS) structure, which is formed by a lithographic process which is described in more detail below.

When the printhead is in use, ink 11 from a reservoir (not shown) enters the chamber 7 via the inlet passage 9, so that the chamber fills to the level as shown in FIG. 1. Thereafter, the heater element 10 is heated for somewhat less than 1 microsecond, so that the heating is in the form of a thermal pulse. It will be appreciated that the heater element 10 is in thermal contact with the ink 11 in the chamber 7 so that when the element is heated, this causes the generation of vapor bubbles 12 in the ink. Accordingly, the ink 11 constitutes a bubble forming liquid. FIG. 1 shows the formation of a bubble 12 approximately 1 microsecond after generation of the thermal pulse, that is, when the bubble has just nucleated on the heater elements 10. It will be appreciated that, as the heat is applied in the form of a pulse, all the energy necessary to generate the bubble 12 is to be supplied within that short time.

When the element 10 is heated as described above, the bubble 12 forms along the length of the element, this bubble appearing, in the cross-sectional view of FIG. 1, as four bubble portions, one for each of the element portions shown in cross section.

The bubble 12, once generated, causes an increase in pressure within the chamber 7, which in turn causes the ejection of a drop 16 of the ink 11 through the nozzle 3. The rim 4 assists in directing the drop 16 as it is ejected, so as to minimize the chance of drop misdirection.

The reason that there is only one nozzle 3 and chamber 7 per inlet passage 9 is so that the pressure wave generated within the chamber, on heating of the element 10 and forming of a bubble 12, does not affect adjacent chambers and their corresponding nozzles. The pressure wave generated within the chamber creates significant stresses in the chamber wall. Forming the chamber from an amorphous ceramic such as silicon nitride, silicon dioxide (glass) or silicon oxynitride, gives the chamber walls high strength while avoiding the use of material with a crystal structure. Crystalline defects can act as stress concentration points and therefore potential areas of weakness and ultimately failure.

FIGS. 2 and 3 show the unit cell 1 at two successive later stages of operation of the printhead. It can be seen that the bubble 12 generates further, and hence grows, with the resultant advancement of ink 11 through the nozzle 3. The shape of the bubble 12 as it grows, as shown in FIG. 3, is determined by a combination of the inertial dynamics and the surface tension of the ink 11. The surface tension tends to minimize the surface area of the bubble 12 so that, by the time a certain amount of liquid has evaporated, the bubble is essentially disk-shaped.

The increase in pressure within the chamber 7 not only pushes ink 11 out through the nozzle 3, but also pushes some ink back through the inlet passage 9. However, the inlet passage 9 is approximately 200 to 300 microns in length, and is only approximately 16 microns in diameter. Hence there is a substantial viscous drag. As a result, the predominant effect of the pressure rise in the chamber 7 is to force ink out through the nozzle 3 as an ejected drop 16, rather than back through the inlet passage 9.

Turning now to FIG. 4, the printhead is shown at a still further successive stage of operation, in which the ink drop 16 that is being ejected is shown during its “necking phase” before the drop breaks off. At this stage, the bubble 12 has already reached its maximum size and has then begun to collapse towards the point of collapse 17, as reflected in more detail in FIG. 21.

The collapsing of the bubble 12 towards the point of collapse 17 causes some ink 11 to be drawn from within the nozzle 3 (from the sides 18 of the drop), and some to be drawn from the inlet passage 9, towards the point of collapse. Most of the ink 11 drawn in this manner is drawn from the nozzle 3, forming an annular neck 19 at the base of the drop 16 prior to its breaking off.

The drop 16 requires a certain amount of momentum to overcome surface tension forces, in order to break off. As ink 11 is drawn from the nozzle 3 by the collapse of the bubble 12, the diameter of the neck 19 reduces thereby reducing the amount of total surface tension holding the drop, so that the momentum of the drop as it is ejected out of the nozzle is sufficient to allow the drop to break off.

When the drop 16 breaks off, cavitation forces are caused as reflected by the arrows 20, as the bubble 12 collapses to the point of collapse 17. It will be noted that there are no solid surfaces in the vicinity of the point of collapse 17 on which the cavitation can have an effect.

Features and Advantages of Further Embodiments

FIGS. 6 to 29 show further embodiments of unit cells 1 for thermal inkjet printheads, each embodiment having its own particular functional advantages. These advantages will be discussed in detail below, with reference to each individual embodiment. For consistency, the same reference numerals are used in FIGS. 6 to 29 to indicate corresponding components.

Referring to FIGS. 6 and 7, the unit cell 1 shown has the chamber 7, ink supply passage 32 and the nozzle rim 4 positioned mid way along the length of the unit cell 1. As best seen in FIG. 7, the drive circuitry 22 is partially on one side of the chamber 7 with the remainder on the opposing side of the chamber. The drive circuitry 22 controls the operation of the heater 14 through vias in the integrated circuit metallisation layers of the interconnect 23. The interconnect 23 has a raised metal layer on its top surface. Passivation layer 24 is formed in top of the interconnect 23 but leaves areas of the raised metal layer exposed. Electrodes 15 of the heater 14 contact the exposed metal areas to supply power to the element 10.

Alternatively, the drive circuitry 22 for one unit cell is not on opposing sides of the heater element that it controls. All the drive circuitry 22 for the heater 14 of one unit cell is in a single, undivided area that is offset from the heater. That is, the drive circuitry 22 is partially overlaid by one of the electrodes 15 of the heater 14 that it is controlling, and partially overlaid by one or more of the heater electrodes 15 from adjacent unit cells. In this situation, the center of the drive circuitry 22 is less than 200 microns from the center of the associate nozzle aperture 5. In most Memjet printheads of this type, the offset is less than 100 microns and in many cases less than 50 microns, preferably less than 30 microns.

Configuring the nozzle components so that there is significant overlap between the electrodes and the drive circuitry provides a compact design with high nozzle density (nozzles per unit area of the nozzle plate 2). This also improves the efficiency of the printhead by shortening the length of the conductors from the circuitry to the electrodes. The shorter conductors have less resistance and therefore dissipate less energy.

The high degree of overlap between the electrodes 15 and the drive circuitry 22 also allows more vias between the heater material and the CMOS metalization layers of the interconnect 23. As best shown in FIGS. 14 and 15, the passivation layer 24 has an array of vias to establish an electrical connection with the heater 14. More vias lowers the resistance between the heater electrodes 15 and the interconnect layer 23 which reduces power losses. However, the passivation layer 24 and electrodes 15 may also be provided without vias in order to simplify the fabrication process.

In FIGS. 8 and 9, the unit cell 1 is the same as that of FIGS. 6 and 7 apart from the heater element 10. The heater element 10 has a bubble nucleation section 158 with a smaller cross section than the remainder of the element. The bubble nucleation section 158 has a greater resistance and heats to a temperature above the boiling point of the ink before the remainder of the element 10. The gas bubble nucleates at this region and subsequently grows to surround the rest of the element 10. By controlling the bubble nucleation and growth, the trajectory of the ejected drop is more predictable.

The heater element 10 is configured to accommodate thermal expansion in a specific manner. As heater elements expand, they will deform to relieve the strain. Elements such as that shown in FIGS. 6 and 7 will bow out of the plane of lamination because its thickness is the thinnest cross sectional dimension and therefore has the least bending resistance. Repeated bending of the element can lead to the formation of cracks, especially at sharp corners, which can ultimately lead to failure. The heater element 10 shown in FIGS. 8 and 9 is configured so that the thermal expansion is relieved by rotation of the bubble nucleation section 158, and slightly splaying the sections leading to the electrodes 15, in preference to bowing out of the plane of lamination. The geometry of the element is such that miniscule bending within the plane of lamination is sufficient to relieve the strain of thermal expansion, and such bending occurs in preference to bowing. This gives the heater element greater longevity and reliability by minimizing bend regions, which are prone to oxidation and cracking.

Referring to FIGS. 10 and 11, the heater element 10 used in this unit cell 1 has a serpentine or ‘double omega’ shape. This configuration keeps the gas bubble centered on the axis of the nozzle. A single omega is a simple geometric shape which is beneficial from a fabrication perspective. However the gap 159 between the ends of the heater element means that the heating of the ink in the chamber is slightly asymmetrical. As a result, the gas bubble is slightly skewed to the side opposite the gap 159. This can in turn affect the trajectory of the ejected drop. The double omega shape provides the heater element with the gap 160 to compensate for the gap 159 so that the symmetry and position of the bubble within the chamber is better controlled and the ejected drop trajectory is more reliable.

FIG. 12 shows a heater element 10 with a single omega shape. As discussed above, the simplicity of this shape has significant advantages during lithographic fabrication. It can be a single current path that is relatively wide and therefore less affected by any inherent inaccuracies in the deposition of the heater material. The inherent inaccuracies of the equipment used to deposit the heater material result in variations in the dimensions of the element. However, these tolerances are fixed values so the resulting variations in the dimensions of a relatively wide component are proportionally less than the variations for a thinner component. It will be appreciated that proportionally large changes of components dimensions will have a greater effect on their intended function. Therefore the performance characteristics of a relatively wide heater element are more reliable than a thinner one.

The omega shape directs current flow around the axis of the nozzle aperture 5. This gives good bubble alignment with the aperture for better ejection of drops while ensuring that the bubble collapse point is not on the heater element 10. As discussed above, this avoids problems caused by cavitation.

Referring to FIGS. 13 to 26, another embodiment of the unit cell 1 is shown together with several stages of the etching and deposition fabrication process. In this embodiment, the heater element 10 is suspended from opposing sides of the chamber. This allows it to be symmetrical about two planes that intersect along the axis of the nozzle aperture 5. This configuration provides a drop trajectory along the axis of the nozzle aperture 5 while avoiding the cavitation problems discussed above.

Fabrication Process

In the interests of brevity, the fabrication stages have been shown for the unit cell of FIG. 13 only (see FIGS. 15 to 25). It will be appreciated that the other unit cells will use the same fabrication stages with different masking

Referring to FIG. 15, there is shown the starting point for fabrication of the thermal inkjet nozzle shown in FIG. 13. CMOS processing of a silicon wafer provides a silicon substrate 21 having drive circuitry 22, and an interlayer dielectric (“interconnect”) 23. The interconnect 23 comprises four metal layers, which together form a seal ring for the inlet passage 9 to be etched through the interconnect. The top metal layer 26, which forms an upper portion of the seal ring, can be seen in FIG. 15. The metal seal ring prevents ink moisture from seeping into the interconnect 23 when the inlet passage 9 is filled with ink.

A passivation layer 24 is deposited onto the top metal layer 26 by plasma-enhanced chemical vapour deposition (PECVD). After deposition of the passivation layer 24, it is etched to define a circular recess, which forms parts of the inlet passage 9. At the same as etching the recess, a plurality of vias 50 are also etched, which allow electrical connection through the passivation layer 24 to the top metal layer 26. The etch pattern is defined by a layer of patterned photoresist (not shown), which is removed by O₂ ashing after the etch.

Referring to FIG. 16, in the next fabrication sequence, a layer of photoresist is spun onto the passivation later 24. The photoresist is exposed and developed to define a circular opening. With the patterned photoresist 51 in place, the dielectric interconnect 23 is etched as far as the silicon substrate 21 using a suitable oxide-etching gas chemistry (e.g. O₂/C₄F₈). Etching through the silicon substrate is continued down to about 20 microns to define a front ink hole 52, using a suitable silicon-etching gas chemistry (e.g. ‘Bosch etch’). The same photoresist mask 51 can be used for both etching steps. FIG. 17 shows the unit cell after etching the front ink hole 52 and removal of the photoresist 51.

Referring to FIG. 18, in the next stage of fabrication, the front ink hole 52 is plugged with photoresist to provide a front plug 53. At the same time, a layer of photoresist is deposited over the passivation layer 24. This layer of photoresist is exposed and developed to define a first sacrificial scaffold 54 over the front plug 53, and scaffolding tracks 35 around the perimeter of the unit cell. The first sacrificial scaffold 54 is used for subsequent deposition of heater material 38 thereon and is therefore formed with a planar upper surface to avoid any buckling in the heater element (see heater element 10 in FIG. 13). The first sacrificial scaffold 54 is UV cured and hardbaked to prevent reflow of the photoresist during subsequent high-temperature deposition onto its upper surface.

Importantly, the first sacrificial scaffold 54 has sloped or angled side faces 55. These angled side faces 55 are formed by adjusting the focusing in the exposure tool (e.g. stepper) when exposing the photoresist. The sloped side faces 55 advantageously allow heater material 38 to be deposited substantially evenly over the first sacrificial scaffold 54.

Referring to FIG. 19, the next stage of fabrication deposits the heater material 38 over the first sacrificial scaffold 54, the passivation layer 24 and the perimeter scaffolding tracks 35. The heater material 38 is typically a monolayer of TiAlN. However, the heater material 38 may alternatively comprise TiAlN sandwiched between upper and lower passivating materials, such as tantalum or tantalum nitride. Passivating layers on the heater element 10 minimize corrosion of the and improve heater longevity.

Referring to FIG. 20, the heater material 38 is subsequently etched down to the first sacrificial scaffold 54 to define the heater element 10. At the same time, contact electrodes 15 are defined on either side of the heater element 10. The electrodes 15 are in contact with the top metal layer 26 and so provide electrical connection between the CMOS and the heater element 10. The sloped side faces of the first sacrificial scaffold 54 ensure good electrical connection between the heater element 10 and the electrodes 15, since the heater material is deposited with sufficient thickness around the scaffold 54. Any thin areas of heater material (due to insufficient side face deposition) would increase resistivity and affect heater performance.

Adjacent unit cells are electrically insulated from each other by virtue of grooves etched around the perimeter of each unit cell. The grooves are etched at the same time as defining the heater element 10.

Referring to FIG. 21, in the subsequent step a second sacrificial scaffold 39 of photoresist is deposited over the heater material. The second sacrificial scaffold 39 is exposed and developed to define sidewalls for the cylindrical nozzle chamber and perimeter sidewalls for each unit cell. The second sacrificial scaffold 39 is also UV cured and hardbaked to prevent any reflow of the photoresist during subsequent high-temperature deposition of the silicon nitride roof material.

Referring to FIG. 22, silicon nitride is deposited onto the second sacrificial scaffold 39 by plasma enhanced chemical vapour deposition. The silicon nitride forms a roof 44 over each unit cell, which is the nozzle plate 2 for a row of nozzles. Chamber sidewalls 6 and unit cell sidewalls 56 are also formed by deposition of silicon nitride.

Referring to FIG. 23, the nozzle rim 4 is etched partially through the roof 44, by placing a suitably patterned photoresist mask over the roof, etching for a controlled period of time and removing the photoresist by ashing.

Referring to FIG. 24, the nozzle aperture 5 is etched through the roof 24 down to the second sacrificial scaffold 39. Again, the etch is performed by placing a suitably patterned photoresist mask over the roof, etching down to the scaffold 39 and removing the photoresist mask.

With the nozzle structure now fully formed on a frontside of the silicon substrate 21, an ink supply channel 32 is etched from the backside of the substrate 21, which meets with the front plug 53.

Referring to FIG. 25, after formation of the ink supply channel 32, the first and second sacrificial scaffolds of photoresist, together with the front plug 53 are ashed off using an O₂ plasma. Accordingly, fluid connection is made from the ink supply channel 32 through to the nozzle aperture 5.

It should be noted that a portion of photoresist, on either side of the nozzle chamber sidewalls 6, remains encapsulated by the roof 44, the unit cell sidewalls 56 and the chamber sidewalls 6. This portion of photoresist is sealed from the O₂ ashing plasma and, therefore, remains intact after fabrication of the printhead. This encapsulated photoresist advantageously provides additional robustness for the printhead by supporting the nozzle plate 2. Hence, the printhead has a robust nozzle plate spanning continuously over rows of nozzles, and being supported by solid blocks of hardened photoresist, in addition to support walls.

Hydrophobic Coating of Front Face

Referring to FIG. 24, it can been seen that a hydrophobic material may be deposited onto the roof 44 at this stage by, for example, chemical vapour deposition. The whole of the front face of the printhead may be coated with hydrophobic material. Alternatively, predetermined regions of the roof 44 (e.g. regions surrounding each nozzle aperture 5) may be coated. However, referring to FIG. 25, the final stage of printhead fabrication involves ashing off the photoresist, which occupies the nozzle chambers. Since hydrophobic coating materials are generally organic in nature, the ashing process will remove the hydrophobic coating on the roof 44 as well as the photoresist 39 in the nozzle chambers. Hence, a hydrophobic coating step at this stage would ultimately have no effect on the hydrophobicity of the roof 44.

Referring to FIG. 25, it can be seen that a hydrophobic material may be deposited onto the roof 44 at this stage by, for example, chemical vapour deposition. However, the CVD process will deposit the hydrophobic material both onto the roof 44, onto nozzle chamber sidewalls, onto the heater element 10 and inside ink supply channels 32. A hydrophobic coating inside the nozzle chambers and ink supply channels would be highly undesirable in terms of creating a positive ink pressure biased towards the nozzle chambers. A hydrophobic coating on the heater element 10 would be equally undesirable in terms of kogation during printing.

Referring to FIG. 27, there is shown a process for depositing a hydrophobic material onto the roof 44, which eliminates the aforementioned selectivity problems. Before deposition of the hydrophobic material, the printhead is primed with a liquid, which fills the ink supply channels 32 and nozzle chamber up to the rim 4. The liquid is preferably ink so that the hydrophobic deposition step can be incorporated into the overall printer manufacturing process. Once primed with ink 60, the front face of the printhead, including the roof 44, is coated with a hydrophobic material 61 by chemical vapour deposition (see FIG. 28). The hydrophobic material 61 cannot be deposited inside the nozzle chamber, because the ink 60 effectively seals the nozzle aperture 5 from the vapour. Hence, the ink 60 protects the nozzle chamber and allows selective deposition of the hydrophobic material 61 onto the roof 44. Accordingly, the final printhead has a hydrophobic front face in combination with hydrophilic nozzle chambers and ink supply channels.

The choice of hydrophobic material is not critical. Any hydrophobic compound, which can adhere to the roof 44 by either covalent bonding, ionic bonding, chemisorption or adsorption may be used. The choice of hydrophobic material will depend on the material forming the roof 44 and also the liquid used to prime the nozzles.

Typically, the roof 44 is formed from silicon nitride, silicon oxide or silicon oxynitride. In this case, the hydrophobic material is typically a compound, which can form covalent bonds with the oxygen or nitrogen atoms exposed on the surface of the roof. Examples of suitable compounds are silyl chlorides (including monochlorides, dichlorides, trichlorides) having at least one hydrophobic group. The hydrophobic group is typically a C₁₋₂₀ alkyl group, optionally substituted with a plurality of fluorine atoms. The hydrophobic group may be perfluorinated, partially fluorinated or non-fluorinated. Examples of suitable hydrophobic compounds include: trimethylsilyl chloride, dimethylsilyl dichloride, methylsilyl trichloride, triethylsilyl chloride, octyldimethylsilyl chloride, perfluorooctyldimethylsilyl chloride, perfluorooctylsilyl trichloride, perfluorooctylchlorosilane etc.

Typically, the nozzles are primed with an inkjet ink. In this case, the hydrophobic material is typically a compound, which does not polymerise in aqueous solution and form a skin across the nozzle aperture 5. Examples of non-polymerizable hydrophobic compounds include: trimethylsilyl chloride, triethylsilyl chloride, perfluorooctyldimethylsilyl chloride, perfluorooctylchlorosilane etc.

Whilst silyl chlorides have been exemplified as hydrophobizing compounds hereinabove, it will be appreciated that the present invention may be used in conjunction with any hydrophobizing compound, which can be deposited by CVD or another suitable deposition process.

Other Embodiments

The invention has been described above with reference to printheads using bubble forming heater elements. However, it is potentially suited to a wide range of printing system including: color and monochrome office printers, short run digital printers, high speed digital printers, offset press supplemental printers, low cost scanning printers high speed pagewidth printers, notebook computers with inbuilt pagewidth printers, portable color and monochrome printers, color and monochrome copiers, color and monochrome facsimile machines, combined printer, facsimile and copying machines, label printers, large format plotters, photograph copiers, printers for digital photographic “minilabs”, video printers, PHOTO CD (PHOTO CD is a registered trade mark of the Eastman Kodak Company) printers, portable printers for PDAs, wallpaper printers, indoor sign printers, billboard printers, fabric printers, camera printers and fault tolerant commercial printer arrays.

It will be appreciated by ordinary workers in this field that numerous variations and/or modifications may be made to the present invention as shown in the specific embodiments without departing from the spirit or scope of the invention as broadly described. The present embodiments are, therefore, to be considered in all respects to be illustrative and not restrictive.

Ink Jet Technologies

The embodiments of the invention use an ink jet printer type device. Of course many different devices could be used.

The most significant problem with thermal ink jet is power consumption. This is approximately 100 times that required for high speed, and stems from the energy-inefficient means of drop ejection. This involves the rapid boiling of water to produce a vapor bubble which expels the ink. Water has a very high heat capacity, and must be superheated in thermal ink jet applications. In conventional thermal inkjet printheads, this leads to an efficiency of around 0.02%, from electricity input to drop momentum (and increased surface area) out.

The most significant problem with piezoelectric ink jet is size and cost. Piezoelectric crystals have a very small deflection at reasonable drive voltages, and therefore require a large area for each nozzle. Also, each piezoelectric actuator must be connected to its drive circuit on a separate substrate. This is not a significant problem at the current limit of around 300 nozzles per printhead, but is a major impediment to the fabrication of pagewidth printheads with 19,200 nozzles.

Ideally, the ink jet technologies used meet the stringent requirements of in-camera digital color printing and other high quality, high speed, low cost printing applications. To meet the requirements of digital photography, new ink jet technologies have been created. The target features include:

low power (less than 10 Watts)

high resolution capability (1,600 dpi or more)

photographic quality output

low manufacturing cost

small size (pagewidth times minimum cross section)

high speed (<2 seconds per page).

All of these features can be met or exceeded by the ink jet systems described below with differing levels of difficulty. Forty-five different ink jet technologies have been developed by the Assignee to give a wide range of choices for high volume manufacture. These technologies form part of separate applications assigned to the present Assignee as set out in the table under the heading Cross References to Related Applications.

The ink jet designs shown here are suitable for a wide range of digital printing systems, from battery powered one-time use digital cameras, through to desktop and network printers, and through to commercial printing systems.

For ease of manufacture using standard process equipment, the printhead is designed to be a monolithic 0.5 micron CMOS chip with MEMS post processing. For color photographic applications, the printhead is 100 mm long, with a width which depends upon the ink jet type. The smallest printhead designed is IJ38, which is 0.35 mm wide, giving a chip area of 35 square mm. The printheads each contain 19,200 nozzles plus data and control circuitry.

Ink is supplied to the back of the printhead by injection molded plastic ink channels. The molding requires 50 micron features, which can be created using a lithographically micromachined insert in a standard injection molding tool Ink flows through holes etched through the wafer to the nozzle chambers fabricated on the front surface of the wafer. The printhead is connected to the camera circuitry by tape automated bonding.

Tables of Drop-on-Demand Ink Jets

Eleven important characteristics of the fundamental operation of individual ink jet nozzles have been identified. These characteristics are largely orthogonal, and so can be elucidated as an eleven dimensional matrix. Most of the eleven axes of this matrix include entries developed by the present assignee.

The following tables form the axes of an eleven dimensional table of ink jet types.

Actuator mechanism (18 types)

Basic operation mode (7 types)

Auxiliary mechanism (8 types)

Actuator amplification or modification method (17 types)

Actuator motion (19 types)

Nozzle refill method (4 types)

Method of restricting back-flow through inlet (10 types)

Nozzle clearing method (9 types)

Nozzle plate construction (9 types)

Drop ejection direction (5 types)

Ink type (7 types)

The complete eleven dimensional table represented by these axes contains 36.9 billion possible configurations of ink jet nozzle. While not all of the possible combinations result in a viable ink jet technology, many million configurations are viable. It is clearly impractical to elucidate all of the possible configurations. Instead, certain ink jet types have been investigated in detail. These are designated IJ01 to IJ45 above which matches the docket numbers in the table under the heading Cross References to Related Applications.

Other ink jet configurations can readily be derived from these forty-five examples by substituting alternative configurations along one or more of the 11 axes. Most of the IJ01 to IJ45 examples can be made into ink jet printheads with characteristics superior to any currently available ink jet technology.

Where there are prior art examples known to the inventor, one or more of these examples are listed in the examples column of the tables below. The IJ01 to IJ45 series are also listed in the examples column. In some cases, print technology may be listed more than once in a table, where it shares characteristics with more than one entry.

Suitable applications for the ink jet technologies include: Home printers, Office network printers, Short run digital printers, Commercial print systems, Fabric printers, Pocket printers, Internet WWW printers, Video printers, Medical imaging, Wide format printers, Notebook PC printers, Fax machines, Industrial printing systems, Photocopiers, Photographic minilabs etc.

The information associated with the aforementioned 11 dimensional matrix are set out in the following tables.

ACTUATOR MECHANISM (APPLIED ONLY TO SELECTED INK DROPS) Description Advantages Disadvantages Examples Thermal An electrothermal Large force High power Canon Bubblejet bubble heater heats the ink to generated Ink carrier 1979 Endo et al GB above boiling point, Simple limited to water patent 2,007,162 transferring significant construction Low efficiency Xerox heater-in- heat to the aqueous No moving parts High pit 1990 Hawkins et ink. A bubble Fast operation temperatures al U.S. Pat. No. nucleates and quickly Small chip area required 4,899,181 forms, expelling the required for actuator High mechanical Hewlett-Packard ink. stress TIJ 1982 Vaught et The efficiency of the Unusual al U.S. Pat. No. process is low, with materials required 4,490,728 typically less than Large drive 0.05% of the electrical transistors energy being Cavitation causes transformed into actuator failure kinetic energy of the Kogation reduces drop. bubble formation Large print heads are difficult to fabricate Piezo- A piezoelectric crystal Low power Very large area Kyser et al electric such as lead consumption required for actuator U.S. Pat. No. 3,946,398 lanthanum zirconate Many ink types Difficult to Zoltan U.S. Pat. (PZT) is electrically can be used integrate with No. 3,683,212 activated, and either Fast operation electronics 1973 Stemme expands, shears, or High efficiency High voltage U.S. Pat. No. 3,747,120 bends to apply drive transistors Epson Stylus pressure to the ink, required Tektronix ejecting drops. Full pagewidth IJ04 print heads impractical due to actuator size Requires electrical poling in high field strengths during manufacture Electro- An electric field is Low power Low maximum Seiko Epson, strictive used to activate consumption strain (approx. Usui et all JP electrostriction in Many ink types 0.01%) 253401/96 relaxor materials such can be used Large area IJ04 as lead lanthanum Low thermal required for actuator zirconate titanate expansion due to low strain (PLZT) or lead Electric field Response speed magnesium niobate strength required is marginal (~10 (PMN). (approx. 3.5 μs) V/μm) High voltage can be generated drive transistors without difficulty required Does not require Full pagewidth electrical poling print heads impractical due to actuator size Ferro- An electric field is Low power Difficult to IJ04 electric used to induce a phase consumption integrate with transition between the Many ink types electronics antiferroelectric (AFE) can be used Unusual and ferroelectric (FE) Fast operation materials such as phase. Perovskite (<1 μs) PLZSnT are materials such as tin Relatively high required modified lead longitudinal strain Actuators require lanthanum zirconate High efficiency a large area titanate (PLZSnT) Electric field exhibit large strains of strength of around 3 up to 1% associated V/μm can be with the AFE to FE readily provided phase transition. Electro- Conductive plates are Low power Difficult to IJ02, IJ04 static plates separated by a consumption operate electrostatic compressible or fluid Many ink types devices in an dielectric (usually air). can be used aqueous Upon application of a Fast operation environment voltage, the plates The electrostatic attract each other and actuator will displace ink, causing normally need to be drop ejection. The separated from the conductive plates may ink be in a comb or Very large area honeycomb structure, required to achieve or stacked to increase high forces the surface area and High voltage therefore the force. drive transistors may be required Full pagewidth print heads are not competitive due to actuator size Electro- A strong electric field Low current High voltage 1989 Saito et al, static pull is applied to the ink, consumption required U.S. Pat. No. 4,799,068 on ink whereupon Low temperature May be damaged 1989 Miura et al, electrostatic attraction by sparks due to air U.S. Pat. No. 4,810,954 accelerates the ink breakdown Tone-jet towards the print Required field medium. strength increases as the drop size decreases High voltage drive transistors required Electrostatic field attracts dust Permanent An electromagnet Low power Complex IJ07, IJ10 magnet directly attracts a consumption fabrication electro- permanent magnet, Many ink types Permanent magnetic displacing ink and can be used magnetic material causing drop ejection. Fast operation such as Neodymium Rare earth magnets High efficiency Iron Boron (NdFeB) with a field strength Easy extension required. around 1 Tesla can be from single nozzles High local used. Examples are: to pagewidth print currents required Samarium Cobalt heads Copper (SaCo) and magnetic metalization should materials in the be used for long neodymium iron boron electromigration family (NdFeB, lifetime and low NdDyFeBNb, resistivity NdDyFeB, etc) Pigmented inks are usually infeasible Operating temperature limited to the Curie temperature (around 540K) Soft A solenoid induced a Low power Complex IJ01, IJ05, IJ08, IJ10 magnetic magnetic field in a soft consumption fabrication IJ12, IJ14, IJ15, IJ17 core electro- magnetic core or yoke Many ink types Materials not magnetic fabricated from a can be used usually present in a ferrous material such Fast operation CMOS fab such as as electroplated iron High efficiency NiFe, CoNiFe, or alloys such as CoNiFe Easy extension CoFe are required [1], CoFe, or NiFe from single nozzles High local alloys. Typically, the to pagewidth print currents required soft magnetic material heads Copper is in two parts, which metalization should are normally held be used for long apart by a spring. electromigration When the solenoid is lifetime and low actuated, the two parts resistivity attract, displacing the Electroplating is ink. required High saturation flux density is required (2.0-2.1 T is achievable with CoNiFe [1]) Lorenz The Lorenz force Low power Force acts as a IJ06, IJ11, IJ13, IJ16 force acting on a current consumption twisting motion carrying wire in a Many ink types Typically, only a magnetic field is can be used quarter of the utilized. Fast operation solenoid length This allows the High efficiency provides force in a magnetic field to be Easy extension useful direction supplied externally to from single nozzles High local the print head, for to pagewidth print currents required example with rare heads Copper earth permanent metalization should magnets. be used for long Only the current electromigration carrying wire need be lifetime and low fabricated on the print- resistivity head, simplifying Pigmented inks materials are usually requirements. infeasible Magneto- The actuator uses the Many ink types Force acts as a Fischenbeck, striction giant magnetostrictive can be used twisting motion U.S. Pat. No. 4,032,929 effect of materials Fast operation Unusual IJ25 such as Terfenol-D (an Easy extension materials such as alloy of terbium, from single nozzles Terfenol-D are dysprosium and iron to pagewidth print required developed at the Naval heads High local Ordnance Laboratory, High force is currents required hence Ter-Fe-NOL). available Copper For best efficiency, the metalization should actuator should be pre- be used for long stressed to approx. 8 electromigration MPa. lifetime and low resistivity Pre-stressing may be required Surface Ink under positive Low power Requires Silverbrook, EP tension pressure is held in a consumption supplementary force 0771 658 A2 and reduction nozzle by surface Simple to effect drop related patent tension. The surface construction separation applications tension of the ink is No unusual Requires special reduced below the materials required in ink surfactants bubble threshold, fabrication Speed may be causing the ink to High efficiency limited by surfactant egress from the Easy extension properties nozzle. from single nozzles to pagewidth print heads Viscosity The ink viscosity is Simple Requires Silverbrook, EP reduction locally reduced to construction supplementary force 0771 658 A2 and select which drops are No unusual to effect drop related patent to be ejected. A materials required in separation applications viscosity reduction can fabrication Requires special be achieved Easy extension ink viscosity electrothermally with from single nozzles properties most inks, but special to pagewidth print High speed is inks can be engineered heads difficult to achieve for a 100:1 viscosity Requires reduction. oscillating ink pressure A high temperature difference (typically 80 degrees) is required Acoustic An acoustic wave is Can operate Complex drive 1993 Hadimioglu generated and without a nozzle circuitry et al, EUP 550,192 focussed upon the plate Complex 1993 Elrod et al, drop ejection region. fabrication EUP 572,220 Low efficiency Poor control of drop position Poor control of drop volume Thermo- An actuator which Low power Efficient aqueous IJ03, IJ09, IJ17, IJ18 elastic bend relies upon differential consumption operation requires a IJ19, IJ20, IJ21, IJ22 actuator thermal expansion Many ink types thermal insulator on IJ23, IJ24, IJ27, IJ28 upon Joule heating is can be used the hot side IJ29, IJ30, IJ31, IJ32 used. Simple planar Corrosion IJ33, IJ34, IJ35, IJ36 fabrication prevention can be IJ37, IJ38 ,IJ39, IJ40 Small chip area difficult IJ41 required for each Pigmented inks actuator may be infeasible, Fast operation as pigment particles High efficiency may jam the bend CMOS actuator compatible voltages and currents Standard MEMS processes can be used Easy extension from single nozzles to pagewidth print heads High CTE A material with a very High force can Requires special IJ09, IJ17, IJ18, IJ20 thermo- high coefficient of be generated material (e.g. PTFE) IJ21, IJ22, IJ23, IJ24 elastic thermal expansion Three methods of Requires a PTFE IJ27, IJ28, IJ29, IJ30 actuator (CTE) such as PTFE deposition are deposition process, IJ31, IJ42, IJ43, IJ44 polytetrafluoroethylene under development: which is not yet (PTFE) is used. As chemical vapor standard in ULSI high CTE materials deposition (CVD), fabs are usually non- spin coating, and PTFE deposition conductive, a heater evaporation cannot be followed fabricated from a PTFE is a candidate with high conductive material is for low dielectric temperature (above incorporated. A 50 μm constant insulation 350° C.) processing long PTFE bend in ULSI Pigmented inks actuator with Very low power may be infeasible, polysilicon heater and consumption as pigment particles 15 mW power input Many ink types may jam the bend can provide 180 can be used actuator μN force Simple planar and 10 μm fabrication deflection. Actuator Small chip area motions include: required for each Bend actuator Push Fast operation Buckle High efficiency Rotate CMOS compatible voltages and currents Easy extension from single nozzles to pagewidth print heads Conductive A polymer with a high High force can Requires special IJ24 polymer coefficient of thermal be generated materials thermo- expansion (such as Very low power development (High elastic PTFE) is doped with consumption CTE conductive actuator conducting substances Many ink types polymer) to increase its can be used Requires a PTFE conductivity to about 3 Simple planar deposition process, orders of magnitude fabrication which is not yet below that of copper. Small chip area standard in ULSI The conducting required for each fabs polymer expands actuator PTFE deposition when resistively Fast operation cannot be followed heated. High efficiency with high Examples of CMOS temperature (above conducting dopants compatible voltages 350° C.) processing include: and currents Evaporation and Carbon nanotubes Easy extension CVD deposition Metal fibers from single nozzles techniques cannot Conductive polymers to pagewidth print be used such as doped heads Pigmented inks polythiophene may be infeasible, Carbon granules as pigment particles may jam the bend actuator Shape A shape memory alloy High force is Fatigue limits IJ26 memory such as TiNi (also available (stresses maximum number alloy known as Nitinol - of hundreds of MPa) of cycles Nickel Titanium alloy Large strain is Low strain (1%) developed at the Naval available (more than is required to extend Ordnance Laboratory) 3%) fatigue resistance is thermally switched High corrosion Cycle rate between its weak resistance limited by heat martensitic state and Simple removal its high stiffness construction Requires unusual austenic state. The Easy extension materials (TiNi) shape of the actuator from single nozzles The latent heat of in its martensitic state to pagewidth print transformation must is deformed relative to heads be provided the austenic shape. Low voltage High current The shape change operation operation causes ejection of a Requires pre- drop. stressing to distort the martensitic state Linear Linear magnetic Linear Magnetic Requires unusual IJ12 Magnetic actuators include the actuators can be semiconductor Actuator Linear Induction constructed with materials such as Actuator (LIA), Linear high thrust, long soft magnetic alloys Permanent Magnet travel, and high (e.g. CoNiFe) Synchronous Actuator efficiency using Some varieties (LPMSA), Linear planar also require Reluctance semiconductor permanent magnetic Synchronous Actuator fabrication materials such as (LRSA), Linear techniques Neodymium iron Switched Reluctance Long actuator boron (NdFeB) Actuator (LSRA), and travel is available Requires the Linear Stepper Medium force is complex multi- Actuator (LSA). available phase drive circuitry Low voltage High current operation operation

BASIC OPERATION MODE Description Advantages Disadvantages Examples Actuator This is the simplest Simple operation Drop repetition Thermal ink jet directly mode of operation: the No external rate is usually Piezoelectric inkjet pushes ink actuator directly fields required limited to around 10 IJ01, IJ02, IJ03, IJ04 supplies sufficient Satellite drops KHz. However, this IJ05, IJ06, IJ07, IJ09 kinetic energy to expel can be avoided if is not fundamental IJ11, IJ12, IJ14, IJ16 the drop. The drop drop velocity is less to the method, but is IJ20, IJ22, IJ23, IJ24 must have a sufficient than 4 m/s related to the refill IJ25, IJ26, IJ27, IJ28 velocity to overcome Can be efficient, method normally IJ29, IJ30, IJ31, IJ32 the surface tension. depending upon the used IJ33, IJ34, IJ35, IJ36 actuator used All of the drop IJ37, IJ38, IJ39, IJ40 kinetic energy must IJ41, IJ42, IJ43, IJ44 be provided by the actuator Satellite drops usually form if drop velocity is greater than 4.5 m/s Proximity The drops to be Very simple print Requires close Silverbrook, EP printed are selected by head fabrication can proximity between 0771 658 A2 and some manner (e.g. be used the print head and related patent thermally induced The drop the print media or applications surface tension selection means transfer roller reduction of does not need to May require two pressurized ink). provide the energy print heads printing Selected drops are required to separate alternate rows of the separated from the ink the drop from the image in the nozzle by nozzle Monolithic color contact with the print print heads are medium or a transfer difficult roller. Electro- The drops to be Very simple print Requires very Silverbrook, EP static pull printed are selected by head fabrication can high electrostatic 0771 658 A2 and on ink some manner (e.g. be used field related patent thermally induced The drop Electrostatic field applications surface tension selection means for small nozzle Tone-Jet reduction of does not need to sizes is above air pressurized ink). provide the energy breakdown Selected drops are required to separate Electrostatic field separated from the ink the drop from the may attract dust in the nozzle by a nozzle strong electric field. Magnetic The drops to be Very simple print Requires Silverbrook, EP pull on ink printed are selected by head fabrication can magnetic ink 0771 658 A2 and some manner (e.g. be used Ink colors other related patent thermally induced The drop than black are applications surface tension selection means difficult reduction of does not need to Requires very pressurized ink). provide the energy high magnetic fields Selected drops are required to separate separated from the ink the drop from the in the nozzle by a nozzle strong magnetic field acting on the magnetic ink. Shutter The actuator moves a High speed (>50 Moving parts are IJ13, IJ17, IJ21 shutter to block ink KHz) operation can required flow to the nozzle. The be achieved due to Requires ink ink pressure is pulsed reduced refill time pressure modulator at a multiple of the Drop timing can Friction and wear drop ejection be very accurate must be considered frequency. The actuator Stiction is energy can be very possible low Shuttered The actuator moves a Actuators with Moving parts are IJ08, IJ15, IJ18, IJ19 grill shutter to block ink small travel can be required flow through a grill to used Requires ink the nozzle. The shutter Actuators with pressure modulator movement need only small force can be Friction and wear be equal to the width used must be considered of the grill holes. High speed (>50 Stiction is KHz) operation can possible be achieved Pulsed A pulsed magnetic Extremely low Requires an IJ10 magnetic field attracts an ‘ink energy operation is external pulsed pull on ink pusher’ at the drop possible magnetic field pusher ejection frequency. An No heat Requires special actuator controls a dissipation materials for both catch, which prevents problems the actuator and the the ink pusher from ink pusher moving when a drop is Complex not to be ejected. construction

AUXILIARY MECHANISM (APPLIED TO ALL NOZZLES) Description Advantages Disadvantages Examples None The actuator directly Simplicity of Drop ejection Most inkjets, fires the ink drop, and construction energy must be including there is no external Simplicity of supplied by piezoelectric and field or other operation individual nozzle thermal bubble. mechanism required. Small physical actuator IJ01, IJ02, IJ03, IJ04, size IJ05, IJ07, IJ09, IJ11 IJ12, IJ14, IJ20, IJ22 IJ23, IJ24, IJ25, IJ26, IJ27, IJ28, IJ29, IJ30, IJ31, IJ32, IJ033, IJ34, IJ35, IJ36, IJ37, IJ38, IJ39, IJ40, IJ41, IJ42, IJ43, IJ44 Oscillating The ink pressure Oscillating ink Requires external Silverbrook, EP ink pressure oscillates, providing pressure can provide ink pressure 0771 658 A2 and (including much of the drop a refill pulse, oscillator related patent acoustic ejection energy. The allowing higher Ink pressure applications stimulation) actuator selects which operating speed phase and amplitude IJ08, IJ13, IJ15, IJ17 drops are to be fired The actuators must be carefully IJ18, IJ19, IJ21 by selectively may operate with controlled blocking or enabling much lower energy Acoustic nozzles. The ink Acoustic lenses reflections in the ink pressure oscillation can be used to focus chamber must be may be achieved by the sound on the designed for vibrating the print nozzles head, or preferably by an actuator in the ink supply. Media The print head is Low power Precision Silverbrook, EP proximity placed in close High accuracy assembly required 0771 658 A2 and proximity to the print Simple print head Paper fibers may related patent medium. Selected construction cause problems applications drops protrude from Cannot print on the print head further rough substrates than unselected drops, and contact the print medium. The drop soaks into the medium fast enough to cause drop separation. Transfer Drops are printed to a High accuracy Bulky Silverbrook, EP roller transfer roller instead Wide range of Expensive 0771 658 A2 and of straight to the print print substrates can Complex related patent medium. A transfer be used construction applications roller can also be used Ink can be dried Tektronix hot for proximity drop on the transfer roller melt piezoelectric separation. inkjet Any of the IJ series Electro- An electric field is Low power Field strength Silverbrook, EP static used to accelerate Simple print head required for 0771 658 A2 and selected drops towards construction separation of small related patent the print medium. drops is near or applications above air breakdown Tone-Jet Direct A magnetic field is Low power Requires Silverbrook, EP magnetic used to accelerate Simple print head magnetic ink 0771 658 A2 and field selected drops of construction Requires strong related patent magnetic ink towards magnetic field applications the print medium. Cross The print head is Does not require Requires external IJ06, IJ16 magnetic placed in a constant magnetic materials magnet field magnetic field. The to be integrated in Current densities Lorenz force in a the print head may be high, current carrying wire manufacturing resulting in is used to move the process electromigration actuator. problems Pulsed A pulsed magnetic Very low power Complex print IJ10 magnetic field is used to operation is possible head construction field cyclically attract a Small print head Magnetic paddle, which pushes size materials required in on the ink. A small print head actuator moves a catch, which selectively prevents the paddle from moving.

ACTUATOR AMPLIFICATION OR MODIFICATION METHOD Description Advantages Disadvantages Examples None No actuator Operational Many actuator Thermal mechanical simplicity mechanisms Bubble Ink jet amplification is have insufficient IJ01, IJ02, used. The actuator travel, or IJ06, IJ07, IJ16, directly drives the insufficient IJ25, IJ26 drop ejection force, to process. efficiently drive the drop ejection process Differential An actuator Provides High stresses Piezoelectric expansion material expands greater travel in are involved IJ03, IJ09, bend more on one side a reduced print Care must be IJ17, IJ18, IJ19, actuator than on the other. head area taken that the IJ20, IJ21, IJ22, The expansion materials do not IJ23, IJ24, IJ27, may be thermal, delaminate IJ29, IJ30, IJ31, piezoelectric, Residual bend IJ32, IJ33, IJ34, magnetostrictive, resulting from IJ35, IJ36, IJ37, or other high temperature IJ38, IJ39, IJ42, mechanism. The or high stress IJ43, IJ44 bend actuator during formation converts a high force low travel actuator mechanism to high travel, lower force mechanism. Transient A trilayer bend Very good High stresses IJ40, IJ41 bend actuator where the temperature are involved actuator two outside layers stability Care must be are identical. This High speed, as taken that the cancels bend due a new drop can materials do not to ambient be fired before delaminate temperature and heat dissipates residual stress. The Cancels actuator only residual stress of responds to formation transient heating of one side or the other. Reverse The actuator loads Better Fabrication IJ05, IJ11 spring a spring. When the coupling to the complexity actuator is turned ink High stress in off, the spring the spring releases. This can reverse the force/distance curve of the actuator to make it compatible with the force/time requirements of the drop ejection. Actuator A series of thin Increased Increased Some stack actuators are travel fabrication piezoelectric ink stacked. This can Reduced drive complexity jets be appropriate voltage Increased IJ04 where actuators possibility of require high short circuits due electric field to pinholes strength, such as electrostatic and piezoelectric actuators. Multiple Multiple smaller Increases the Actuator IJ12, IJ13, actuators actuators are used force available forces may not IJ18, IJ20, IJ22, simultaneously to from an actuator add linearly, IJ28, IJ42, IJ43 move the ink. Each Multiple reducing actuator need actuators can be efficiency provide only a positioned to portion of the control ink flow force required. accurately Linear A linear spring is Matches low Requires print IJ15 Spring used to transform a travel actuator head area for the motion with small with higher spring travel and high travel force into a longer requirements travel, lower force Non-contact motion. method of motion transformation Coiled A bend actuator is Increases Generally IJ17, IJ21, actuator coiled to provide travel restricted to IJ34, IJ35 greater travel in a Reduces chip planar reduced chip area. area implementations Planar due to extreme implementations fabrication are relatively difficulty in easy to fabricate. other orientations. Flexure A bend actuator Simple means Care must be IJ10, IJ19, bend has a small region of increasing taken not to IJ33 actuator near the fixture travel of a bend exceed the point, which flexes actuator elastic limit in much more readily the flexure area than the remainder Stress of the actuator. distribution is The actuator very uneven flexing is Difficult to effectively accurately model converted from an with finite even coiling to an element analysis angular bend, resulting in greater travel of the actuator tip. Catch The actuator Very low Complex IJ10 controls a small actuator energy construction catch. The catch Very small Requires either enables or actuator size external force disables movement Unsuitable for of an ink pusher pigmented inks that is controlled in a bulk manner. Gears Gears can be used Low force, Moving parts IJ13 to increase travel low travel are required at the expense of actuators can be Several duration. Circular used actuator cycles gears, rack and Can be are required pinion, ratchets, fabricated using More complex and other gearing standard surface drive electronics methods can be MEMS Complex used. processes construction Friction, friction, and wear are possible Buckle A buckle plate can Very fast Must stay S. Hirata et al, plate be used to change movement within elastic “An Ink-jet a slow actuator achievable limits of the Head Using into a fast motion. materials for Diaphragm It can also convert long device life Microactuator”, a high force, low High stresses Proc. IEEE travel actuator into involved MEMS, February a high travel, Generally 1996, pp 418-423. medium force high power IJ18, IJ27 motion. requirement Tapered A tapered Linearizes the Complex IJ14 magnetic magnetic pole can magnetic construction pole increase travel at force/distance the expense of curve force. Lever A lever and Matches low High stress IJ32, IJ36, fulcrum is used to travel actuator around the IJ37 transform a motion with higher fulcrum with small travel travel and high force into requirements a motion with Fulcrum area longer travel and has no linear lower force. The movement, and lever can also can be used for a reverse the fluid seal direction of travel. Rotary The actuator is High Complex IJ28 impeller connected to a mechanical construction rotary impeller. A advantage Unsuitable for small angular The ratio of pigmented inks deflection of the force to travel of actuator results in the actuator can a rotation of the be matched to impeller vanes, the nozzle which push the ink requirements by against stationary varying the vanes and out of number of the nozzle. impeller vanes Acoustic A refractive or No moving Large area 1993 lens diffractive (e.g. parts required Hadimioglu et zone plate) Only relevant al, EUP 550,192 acoustic lens is for acoustic ink 1993 Elrod et used to concentrate jets al, EUP 572,220 sound waves. Sharp A sharp point is Simple Difficult to Tone-jet conductive used to concentrate construction fabricate using point an electrostatic standard VLSI field. processes for a surface ejecting ink-jet Only relevant for electrostatic ink jets

ACTUATOR MOTION Description Advantages Disadvantages Examples Volume The volume of the Simple High energy is Hewlett- expansion actuator changes, construction in typically Packard Thermal pushing the ink in the case of required to Ink jet all directions. thermal ink jet achieve volume Canon expansion. This Bubblejet leads to thermal stress, cavitation, and kogation in thermal ink jet implementations Linear, The actuator Efficient High IJ01, IJ02, normal to moves in a coupling to ink fabrication IJ04, IJ07, IJ11, chip direction normal to drops ejected complexity may IJ14 surface the print head normal to the be required to surface. The surface achieve nozzle is typically perpendicular in the line of motion movement. Parallel to The actuator Suitable for Fabrication IJ12, IJ13, chip moves parallel to planar complexity IJ15, IJ33,, IJ34, surface the print head fabrication Friction IJ35, IJ36 surface. Drop Stiction ejection may still be normal to the surface. Membrane An actuator with a The effective Fabrication 1982 Howkins push high force but area of the complexity U.S. Pat. No. 4,459,601 small area is used actuator Actuator size to push a stiff becomes the Difficulty of membrane that is membrane area integration in a in contact with the VLSI process ink. Rotary The actuator Rotary levers Device IJ05, IJ08, causes the rotation may be used to complexity IJ13, IJ28 of some element, increase travel May have such a grill or Small chip friction at a pivot impeller area point requirements Bend The actuator bends A very small Requires the 1970 Kyser et when energized. change in actuator to be al U.S. Pat. No. This may be due to dimensions can made from at 3,946,398 differential be converted to a least two distinct 1973 Stemme thermal expansion, large motion. layers, or to have U.S. Pat. No. 3,747,120 piezoelectric a thermal IJ03, IJ09, expansion, difference across IJ10, IJ19, IJ23, magnetostriction, the actuator IJ24, IJ25, IJ29, or other form of IJ30, IJ31, IJ33, relative IJ34, IJ35 dimensional change. Swivel The actuator Allows Inefficient IJ06 swivels around a operation where coupling to the central pivot. This the net linear ink motion motion is suitable force on the where there are paddle is zero opposite forces Small chip applied to opposite area sides of the paddle, requirements e.g. Lorenz force. Straighten The actuator is Can be used Requires IJ26, IJ32 normally bent, and with shape careful balance straightens when memory alloys of stresses to energized. where the ensure that the austenic phase is quiescent bend is planar accurate Double The actuator bends One actuator Difficult to IJ36, IJ37, bend in one direction can be used to make the drops IJ38 when one element power two ejected by both is energized, and nozzles. bend directions bends the other Reduced chip identical. way when another size. A small element is Not sensitive efficiency loss energized. to ambient compared to temperature equivalent single bend actuators. Shear Energizing the Can increase Not readily 1985 Fishbeck actuator causes a the effective applicable to U.S. Pat. No. 4,584,590 shear motion in the travel of other actuator actuator material. piezoelectric mechanisms actuators Radial The actuator Relatively High force 1970 Zoltan constriction squeezes an ink easy to fabricate required U.S. Pat. No. 3,683,212 reservoir, forcing single nozzles Inefficient ink from a from glass Difficult to constricted nozzle. tubing as integrate with macroscopic VLSI processes structures Coil/ A coiled actuator Easy to Difficult to IJ17, IJ21, uncoil uncoils or coils fabricate as a fabricate for IJ34, IJ35 more tightly. The planar VLSI non-planar motion of the free process devices end of the actuator Small area Poor out-of- ejects the ink. required, plane stiffness therefore low cost Bow The actuator bows Can increase Maximum IJ16, IJ18, (or buckles) in the the speed of travel is IJ27 middle when travel constrained energized. Mechanically High force rigid required Push-Pull Two actuators The structure Not readily IJ18 control a shutter. is pinned at both suitable for ink One actuator pulls ends, so has a jets which the shutter, and the high out-of- directly push the other pushes it. plane rigidity ink Curl A set of actuators Good fluid Design IJ20, IJ42 inwards curl inwards to flow to the complexity reduce the volume region behind of ink that they the actuator enclose. increases efficiency Curl A set of actuators Relatively Relatively IJ43 outwards curl outwards, simple large chip area pressurizing ink in construction a chamber surrounding the actuators, and expelling ink from a nozzle in the chamber. Iris Multiple vanes High High IJ22 enclose a volume efficiency fabrication of ink. These Small chip complexity simultaneously area Not suitable rotate, reducing for pigmented the volume inks between the vanes. Acoustic The actuator The actuator Large area 1993 vibration vibrates at a high can be required for Hadimioglu et frequency. physically efficient al, EUP 550,192 distant from the operation at 1993 Elrod et ink useful al, EUP 572,220 frequencies Acoustic coupling and crosstalk Complex drive circuitry Poor control of drop volume and position None In various ink jet No moving Various other Silverbrook, designs the parts tradeoffs are EP 0771 658 A2 actuator does not required to and related move. eliminate patent moving parts applications Tone-jet

NOZZLE REFILL METHOD Description Advantages Disadvantages Examples Surface This is the normal Fabrication Low speed Thermal ink tension way that ink jets simplicity Surface jet are refilled. After Operational tension force Piezoelectric the actuator is simplicity relatively small ink jet energized, it compared to IJ01-IJ07, typically returns actuator force IJ10-IJ14, IJ16, rapidly to its Long refill IJ20, IJ22-IJ45 normal position. time usually This rapid return dominates the sucks in air total repetition through the nozzle rate opening. The ink surface tension at the nozzle then exerts a small force restoring the meniscus to a minimum area. This force refills the nozzle. Shuttered Ink to the nozzle High speed Requires IJ08, IJ13, oscillating chamber is Low actuator common ink IJ15, IJ17, IJ18, ink provided at a energy, as the pressure IJ19, IJ21 pressure pressure that actuator need oscillator oscillates at twice only open or May not be the drop ejection close the shutter, suitable for frequency. When a instead of pigmented inks drop is to be ejecting the ink ejected, the shutter drop is opened for 3 half cycles: drop ejection, actuator return, and refill. The shutter is then closed to prevent the nozzle chamber emptying during the next negative pressure cycle. Refill After the main High speed, as Requires two IJ09 actuator actuator has the nozzle is independent ejected a drop a actively refilled actuators per second (refill) nozzle actuator is energized. The refill actuator pushes ink into the nozzle chamber. The refill actuator returns slowly, to prevent its return from emptying the chamber again. Positive The ink is held a High refill Surface spill Silverbrook, ink slight positive rate, therefore a must be EP 0771 658 A2 pressure pressure. After the high drop prevented and related ink drop is ejected, repetition rate is Highly patent the nozzle possible hydrophobic applications chamber fills print head Alternative quickly as surface surfaces are for:, IJ01-IJ07, tension and ink required IJ10-IJ14, IJ16, pressure both IJ20, IJ22-IJ45 operate to refill the nozzle.

METHOD OF RESTRICTING BACK-FLOW THROUGH INLET Description Advantages Disadvantages Examples Long inlet The ink inlet Design Restricts refill Thermal ink channel channel to the simplicity rate jet nozzle chamber is Operational May result in Piezoelectric made long and simplicity a relatively large ink jet relatively narrow, Reduces chip area IJ42, IJ43 relying on viscous crosstalk Only partially drag to reduce effective inlet back-flow. Positive The ink is under a Drop selection Requires a Silverbrook, ink positive pressure, and separation method (such as EP 0771 658 A2 pressure so that in the forces can be a nozzle rim or and related quiescent state reduced effective patent some of the ink Fast refill time hydrophobizing, applications drop already or both) to Possible protrudes from the prevent flooding operation of the nozzle. of the ejection following: IJ01-IJ07, This reduces the surface of the IJ09-IJ12, pressure in the print head. IJ14, IJ16, IJ20, nozzle chamber IJ22,, IJ23-IJ34, which is required IJ36-IJ41, IJ44 to eject a certain volume of ink. The reduction in chamber pressure results in a reduction in ink pushed out through the inlet. Baffle One or more The refill rate Design HP Thermal baffles are placed is not as complexity Ink Jet in the inlet ink restricted as the May increase Tektronix flow. When the long inlet fabrication piezoelectric ink actuator is method. complexity (e.g. jet energized, the Reduces Tektronix hot rapid ink crosstalk melt movement creates Piezoelectric eddies which print heads). restrict the flow through the inlet. The slower refill process is unrestricted, and does not result in eddies. Flexible In this method Significantly Not applicable Canon flap recently disclosed reduces back- to most ink jet restricts by Canon, the flow for edge- configurations inlet expanding actuator shooter thermal Increased (bubble) pushes on ink jet devices fabrication a flexible flap that complexity restricts the inlet. Inelastic deformation of polymer flap results in creep over extended use Inlet filter A filter is located Additional Restricts refill IJ04, IJ12, between the ink advantage of ink rate IJ24, IJ27, IJ29, inlet and the filtration May result in IJ30 nozzle chamber. Ink filter may complex The filter has a be fabricated construction multitude of small with no holes or slots, additional restricting ink process steps flow. The filter also removes particles which may block the nozzle. Small The ink inlet Design Restricts refill IJ02, IJ37, inlet channel to the simplicity rate IJ44 compared nozzle chamber May result in to nozzle has a substantially a relatively large smaller cross chip area section than that of Only partially the nozzle, effective resulting in easier ink egress out of the nozzle than out of the inlet. Inlet A secondary Increases Requires IJ09 shutter actuator controls speed of the ink- separate refill the position of a jet print head actuator and shutter, closing off operation drive circuit the ink inlet when the main actuator is energized. The inlet The method avoids Back-flow Requires IJ01, IJ03, is located the problem of problem is careful design to IJ05, IJ06, IJ07, behind inlet back-flow by eliminated minimize the IJ10, IJ11, IJ14, the ink- arranging the ink- negative IJ16, IJ22, IJ23, pushing pushing surface of pressure behind IJ25, IJ28, IJ31, surface the actuator the paddle IJ32, IJ33, IJ34, between the inlet IJ35, IJ36, IJ39, and the nozzle. IJ40, IJ41 Part of The actuator and a Significant Small increase IJ07, IJ20, the wall of the ink reductions in in fabrication IJ26, IJ38 actuator chamber are back-flow can be complexity moves to arranged so that achieved shut off the motion of the Compact the inlet actuator closes off designs possible the inlet. Nozzle In some Ink back-flow None related Silverbrook, actuator configurations of problem is to ink back-flow EP 0771 658 A2 does not ink jet, there is no eliminated on actuation and related result in expansion or patent ink back- movement of an applications flow actuator which Valve-jet may cause ink Tone-jet back-flow through the inlet.

NOZZLE CLEARING METHOD Description Advantages Disadvantages Examples Normal All of the nozzles No added May not be Most ink jet nozzle are fired complexity on sufficient to systems firing periodically, the print head displace dried IJ01, IJ02, before the ink has ink IJ03, IJ04, IJ05, a chance to dry. IJ06, IJ07, IJ09, When not in use IJ10, IJ11, IJ12, the nozzles are IJ14, IJ16, IJ20, sealed (capped) IJ22, IJ23, IJ24, against air. IJ25, IJ26, IJ27, The nozzle firing IJ28, IJ29, IJ30, is usually IJ31, IJ32, IJ33, performed during a IJ34, IJ36, IJ37, special clearing IJ38, IJ39, IJ40,, cycle, after first IJ41, IJ42, IJ43, moving the print IJ44,, IJ45 head to a cleaning station. Extra In systems which Can be highly Requires Silverbrook, power to heat the ink, but do effective if the higher drive EP 0771 658 A2 ink heater not boil it under heater is voltage for and related normal situations, adjacent to the clearing patent nozzle clearing can nozzle May require applications be achieved by larger drive over-powering the transistors heater and boiling ink at the nozzle. Rapid The actuator is Does not Effectiveness May be used succession fired in rapid require extra depends with: IJ01, IJ02, of succession. In drive circuits on substantially IJ03, IJ04, IJ05, actuator some the print head upon the IJ06, IJ07, IJ09, pulses configurations, this Can be readily configuration of IJ10, IJ11, IJ14, may cause heat controlled and the ink jet nozzle IJ16, IJ20, IJ22, build-up at the initiated by IJ23, IJ24, IJ25, nozzle which boils digital logic IJ27, IJ28, IJ29, the ink, clearing IJ30, IJ31, IJ32, the nozzle. In other IJ33, IJ34, IJ36, situations, it may IJ37, IJ38, IJ39, cause sufficient IJ40, IJ41, IJ42, vibrations to IJ43, IJ44, IJ45 dislodge clogged nozzles. Extra Where an actuator A simple Not suitable May be used power to is not normally solution where where there is a with: IJ03, IJ09, ink driven to the limit applicable hard limit to IJ16, IJ20, IJ23, pushing of its motion, actuator IJ24, IJ25, IJ27, actuator nozzle clearing movement IJ29, IJ30, IJ31, may be assisted by IJ32, IJ39, IJ40, providing an IJ41, IJ42, IJ43, enhanced drive IJ44, IJ45 signal to the actuator. Acoustic An ultrasonic A high nozzle High IJ08, IJ13, resonance wave is applied to clearing implementation IJ15, IJ17, IJ18, the ink chamber. capability can be cost if system IJ19, IJ21 This wave is of an achieved does not already appropriate May be include an amplitude and implemented at acoustic actuator frequency to cause very low cost in sufficient force at systems which the nozzle to clear already include blockages. This is acoustic easiest to achieve actuators if the ultrasonic wave is at a resonant frequency of the ink cavity. Nozzle A microfabricated Can clear Accurate Silverbrook, clearing plate is pushed severely clogged mechanical EP 0771 658 A2 plate against the nozzles alignment is and related nozzles. The plate required patent has a post for Moving parts applications every nozzle. A are required post moves There is risk through each of damage to the nozzle, displacing nozzles dried ink. Accurate fabrication is required Ink The pressure of the May be Requires May be used pressure ink is temporarily effective where pressure pump with all IJ series pulse increased so that other methods or other pressure ink jets ink streams from cannot be used actuator all of the nozzles. Expensive This may be used Wasteful of in conjunction ink with actuator energizing. Print A flexible ‘blade’ Effective for Difficult to Many ink jet head is wiped across the planar print head use if print head systems wiper print head surface. surfaces surface is non- The blade is Low cost planar or very usually fabricated fragile from a flexible Requires polymer, e.g. mechanical parts rubber or synthetic Blade can elastomer. wear out in high volume print systems Separate A separate heater Can be Fabrication Can be used ink is provided at the effective where complexity with many IJ boiling nozzle although other nozzle series ink jets heater the normal drop e- clearing methods ection mechanism cannot be used does not require it. Can be The heaters do not implemented at require individual no additional drive circuits, as cost in some ink many nozzles can jet be cleared configurations simultaneously, and no imaging is required.

NOZZLE PLATE CONSTRUCTION Description Advantages Disadvantages Examples Electro- A nozzle plate is Fabrication High Hewlett formed separately simplicity temperatures and Packard Thermal nickel fabricated from pressures are Ink jet electroformed required to bond nickel, and bonded nozzle plate to the print head Minimum chip. thickness constraints Differential thermal expansion Laser Individual nozzle No masks Each hole Canon ablated or holes are ablated required must be Bubblejet drilled by an intense UV Can be quite individually 1988 Sercel et polymer laser in a nozzle fast formed al., SPIE, Vol. plate, which is Some control Special 998 Excimer typically a over nozzle equipment Beam polymer such as profile is required Applications, pp. polyimide or possible Slow where 76-83 polysulphone Equipment there are many 1993 required is thousands of Watanabe et al., relatively low nozzles per print U.S. Pat. No. 5,208,604 cost head May produce thin burrs at exit holes Silicon A separate nozzle High accuracy Two part K. Bean, micro- plate is is attainable construction IEEE machined micromachined High cost Transactions on from single crystal Requires Electron silicon, and precision Devices, Vol. bonded to the print alignment ED-25, No. 10, head wafer. Nozzles may 1978, pp 1185-1195 be clogged by Xerox 1990 adhesive Hawkins et al., U.S. Pat. No. 4,899,181 Glass Fine glass No expensive Very small 1970 Zoltan capillaries capillaries are equipment nozzle sizes are U.S. Pat. No. 3,683,212 drawn from glass required difficult to form tubing. This Simple to Not suited for method has been make single mass production used for making nozzles individual nozzles, but is difficult to use for bulk manufacturing of print heads with thousands of nozzles. Monolithic, The nozzle plate is High accuracy Requires Silverbrook, surface deposited as a (<1 μm) sacrificial layer EP 0771 658 A2 micro- layer using Monolithic under the nozzle and related machined standard VLSI Low cost plate to form the patent using deposition Existing nozzle chamber applications VLSI techniques. processes can be Surface may IJ01, IJ02, litho- Nozzles are etched used be fragile to the IJ04, IJ11, IJ12, graphic in the nozzle plate touch IJ17, IJ18, IJ20, processes using VLSI IJ22, IJ24, IJ27, lithography and IJ28, IJ29, IJ30, etching. IJ31, IJ32, IJ33, IJ34, IJ36, IJ37, IJ38, IJ39, IJ40, IJ41, IJ42, IJ43, IJ44 Monolithic, The nozzle plate is High accuracy Requires long IJ03, IJ05, etched a buried etch stop (<1 μm) etch times IJ06, IJ07, IJ08, through in the wafer. Monolithic Requires a IJ09, IJ10, IJ13, substrate Nozzle chambers Low cost support wafer IJ14, IJ15, IJ16, are etched in the No differential IJ19, IJ21, IJ23, front of the wafer, expansion IJ25, IJ26 and the wafer is thinned from the back side. Nozzles are then etched in the etch stop layer. No nozzle Various methods No nozzles to Difficult to Ricoh 1995 plate have been tried to become clogged control drop Sekiya et al U.S. Pat. No. eliminate the position 5,412,413 nozzles entirely, to accurately 1993 prevent nozzle Crosstalk Hadimioglu et al clogging. These problems EUP 550,192 include thermal 1993 Elrod et bubble al EUP 572,220 mechanisms and acoustic lens mechanisms Trough Each drop ejector Reduced Drop firing IJ35 has a trough manufacturing direction is through which a complexity sensitive to paddle moves. Monolithic wicking. There is no nozzle plate. Nozzle slit The elimination of No nozzles to Difficult to 1989 Saito et instead of nozzle holes and become clogged control drop al U.S. Pat. No. individual replacement by a position 4,799,068 nozzles slit encompassing accurately many actuator Crosstalk positions reduces problems nozzle clogging, but increases crosstalk due to ink surface waves

DROP EJECTION DIRECTION Description Advantages Disadvantages Examples Edge Ink flow is along Simple Nozzles Canon (‘edge the surface of the construction limited to edge Bubblejet 1979 shooter’) chip, and ink drops No silicon High Endo et al GB are ejected from etching required resolution is patent 2,007,162 the chip edge. Good heat difficult Xerox heater- sinking via Fast color in-pit 1990 substrate printing requires Hawkins et al Mechanically one print head U.S. Pat. No. 4,899,181 strong per color Tone-jet Ease of chip handing Surface Ink flow is along No bulk Maximum ink Hewlett- (‘roof the surface of the silicon etching flow is severely Packard TIJ shooter’) chip, and ink drops required restricted 1982 Vaught et are ejected from Silicon can al U.S. Pat. No. the chip surface, make an 4,490,728 normal to the effective heat IJ02, IJ11, plane of the chip. sink IJ12, IJ20, IJ22 Mechanical strength Through Ink flow is through High ink flow Requires bulk Silverbrook, chip, the chip, and ink Suitable for silicon etching EP 0771 658 A2 forward drops are ejected pagewidth print and related (‘up from the front heads patent shooter’) surface of the chip. High nozzle applications packing density IJ04, IJ17, therefore low IJ18, IJ24, IJ27-IJ45 manufacturing cost Through Ink flow is through High ink flow Requires IJ01, IJ03, chip, the chip, and ink Suitable for wafer thinning IJ05, IJ06, IJ07, reverse drops are ejected pagewidth print Requires IJ08, IJ09, IJ10, (‘down from the rear heads special handling IJ13, IJ14, IJ15, shooter’) surface of the chip. High nozzle during IJ16, IJ19, IJ21, packing density manufacture IJ23, IJ25, IJ26 therefore low manufacturing cost Through Ink flow is through Suitable for Pagewidth Epson Stylus actuator the actuator, which piezoelectric print heads Tektronix hot is not fabricated as print heads require several melt part of the same thousand piezoelectric ink substrate as the connections to jets drive transistors. drive circuits Cannot be manufactured in standard CMOS fabs Complex assembly required

INK TYPE Description Advantages Disadvantages Examples Aqueous, Water based ink Environmentally Slow drying Most existing dye which typically friendly Corrosive ink jets contains: water, No odor Bleeds on All IJ series dye, surfactant, paper ink jets humectant, and May Silverbrook, biocide. strikethrough EP 0771 658 A2 Modern ink dyes Cockles paper and related have high water- patent fastness, light applications fastness Aqueous, Water based ink Environmentally Slow drying IJ02, IJ04, pigment which typically friendly Corrosive IJ21, IJ26, IJ27, contains: water, No odor Pigment may IJ30 pigment, Reduced bleed clog nozzles Silverbrook, surfactant, Reduced Pigment may EP 0771 658 A2 humectant, and wicking clog actuator and related biocide. Reduced mechanisms patent Pigments have an strikethrough Cockles paper applications advantage in Piezoelectric reduced bleed, ink-jets wicking and Thermal ink strikethrough. jets (with significant restrictions) Methyl MEK is a highly Very fast Odorous All IJ series Ethyl volatile solvent drying Flammable ink jets Ketone used for industrial Prints on (MEK) printing on various difficult surfaces substrates such such as aluminum as metals and cans. plastics Alcohol Alcohol based inks Fast drying Slight odor All IJ series (ethanol, can be used where Operates at Flammable ink jets 2-butanol, the printer must sub-freezing and operate at temperatures others) temperatures Reduced below the freezing paper cockle point of water. An Low cost example of this is in-camera consumer photographic printing. Phase The ink is solid at No drying High viscosity Tektronix hot change room temperature, time-ink Printed ink melt (hot melt) and is melted in instantly freezes typically has a piezoelectric ink the print head on the print ‘waxy’ feel jets before jetting. Hot medium Printed pages 1989 Nowak melt inks are Almost any may ‘block’ U.S. Pat. No. 4,820,346 usually wax based, print medium Ink All IJ series with a melting can be used temperature may ink jets point around 80° C. No paper be above the After jetting cockle occurs curie point of the ink freezes No wicking permanent almost instantly occurs magnets upon contacting No bleed Ink heaters the print medium occurs consume power or a transfer roller. No Long warm- strikethrough up time occurs Oil Oil based inks are High High All IJ series extensively used in solubility viscosity: this is ink jets offset printing. medium for a significant They have some dyes limitation for use advantages in Does not in ink jets, which improved cockle paper usually require a characteristics on Does not wick low viscosity. paper (especially through paper Some short no wicking or chain and multi- cockle). Oil branched oils soluble dies and have a pigments are sufficiently low required. viscosity. Slow drying Micro- A microemulsion Stops ink Viscosity All IJ series emulsion is a stable, self bleed higher than ink jets forming emulsion High dye water of oil, water, and solubility Cost is surfactant. The Water, oil, slightly higher characteristic drop and amphiphilic than water based size is less than soluble dies can ink 100 nm, and is be used High determined by the Can stabilize surfactant preferred curvature pigment concentration of the surfactant. suspensions required (around 5%) 

1. A method of hydrophobizing an ejection face of a printhead, whilst avoiding hydrophobizing fluid distribution structures of the printhead, the method comprising the steps of: (a) filling fluid distribution structures of the printhead exposed to the ejection face with a liquid; and (b) depositing a hydrophobizing material onto the ejection face of the printhead, provided that step (a) is performed prior to step (b).
 2. A method according to claim 1, wherein the fluid distribution structures comprise ejection nozzle chambers and fluid supply channels of the printhead.
 3. A method according to claim 2 wherein the liquid is an inkjet ink.
 4. A method according to claim 3,wherein step (a) includes priming the chambers with the inkjet ink.
 5. A method according to claim 1, wherein the deposition of step (b) is chemical vapor deposition.
 6. A method according to claim 1, wherein the ejection face comprises atoms available for covalent bonding with the hydrophobizing material.
 7. A method according to claim 6, wherein the atoms are oxygen or nitrogen atoms.
 8. A method according to claim 6, wherein the hydrophobizing material forms covalent bonds with the ejection face.
 9. A method according to claim 6, wherein the ejection face is comprised of a material selected from silicon nitride, silicon oxide or silicon oxynitride. 